COURSE UNIT TITLE

: TETRAPYRROLE DERIVATIVES: PORPHYRIN AND PHTHALOCYANINE CHEMISTRY

Description of Individual Course Units

Course Unit Code Course Unit Title Type Of Course D U L ECTS
KIM 5120 TETRAPYRROLE DERIVATIVES: PORPHYRIN AND PHTHALOCYANINE CHEMISTRY ELECTIVE 3 0 0 8

Offered By

Graduate School of Natural and Applied Sciences

Level of Course Unit

Second Cycle Programmes (Master's Degree)

Course Coordinator

ASSOCIATE PROFESSOR DERYA TOPKAYA TAŞKIRAN

Offered to

Chemistry
Chemistry
Chemistry

Course Objective

The porphyrins and phthalocyanines are among the most representative macrocycles in synthetic chemistry, characterized by specific molecular structures, responsible and associated with their particular properties. They have high versatility and an adequate variability introduced either by macrocycle metallation or by different substituents at its periphery called meso-substituents. The porphyrins could find, together with the synthetic phthalocyanines, various scientific and technological applications in chemical and photochemical areas. They can serve as catalysts and photocatalysts in different reactions, or as photosensitizers in photodynamic therapy of cancer, due to their high efficiency to generate free radicals and excited state species. To clarify the structure and properties of phthalocyanines and porphyrins which are the most important of macrocyclic compounds which have a lot of technological value and potential applications.

Learning Outcomes of the Course Unit

1   Review the literature carefully in accordance with the research project and make a connection between its own results and previous literatüre
2   Ftalosiyaninlerin ve porfirinlerin literatürdeki yeri hakkında bilgi edinmek
3   To propose synthesis and purification ways and to make appropriate analysis of target applications.
4   To have knowledge about the application areas of phthalocyanines and porphyrins
5   To gain knowledge in the chemistry of tetrapyrolic derivatives.

Mode of Delivery

Face -to- Face

Prerequisites and Co-requisites

None

Recomended Optional Programme Components

None

Course Contents

Week Subject Description
1 Definition and history of phthalocyanines and porphyrins
2 Nomenclature of Phthalocyanines Porphyrins
3 Synthesis methods of phthalocyanines
4 Starting materials used in the synthesis of phthalocyanine and synthesis of these substances
5 Formation mechanism of phthalocyanines
6 Formation mechanism of porphyrins and methods used in the synthesis of porphyrins.
7 Methods for Purification of Phthalocyanines and Porphyrins
8 Physical and Chemical Properties of Phthalocyanines and Porphyrins
9 Spectroscopy of phthalocyanines and porphyrins: UV, NMR, IR
10 The place of phthalocyanines in the literature and studies on phthalocyanines in the literature
11 The role of porphyrins in the literature and studies on phthalocyanines in the literature
12 Homework Presentation
13 Homework Presentation
14 Final examination

Recomended or Required Reading

1. Leznoff CC and Lever ABP, (eds). Phthalocyanines:Properties and Applications, vols 1-4.VCH: New York, 1989, 1993, 1993, 1996.
2. Frank H. Moser and Arthur L. Thomas, (edu). The Phthalocyanines, vols 1,2. CRC
Pres, 1983.
Supplementary Book(s): Handbook of Porphyrin Science (World Scientific)
Referanslar:
References:
Materials: Other organic dyes and pigments books, Ppt presentations which published on the internet

Planned Learning Activities and Teaching Methods

Pressentation, describing the subject, question-answer, sampling, homework

Assessment Methods

SORTING NUMBER SHORT CODE LONG CODE FORMULA
1 PRS PRESENTATION
2 ASG ASSIGNMENT
3 FCG FINAL COURSE GRADE PRS * 0.50 + ASG * 0.50


*** Resit Exam is Not Administered in Institutions Where Resit is not Applicable.

Further Notes About Assessment Methods

None

Assessment Criteria

To be announced.

Language of Instruction

Turkish

Course Policies and Rules

During the semester, the responsibility to continues 70% of the courses is student s self-owned. And must be observed the specified time about course times. Unethical behavior that may occur in class and on exams, will be acting within the framework of the relevant regulations. Teaching and examination implementation principles regulations of D.E.Ü Graduate School of Natural and Applied Sciences can be found at Graduate School of Natural and Applied Sciences web page.

Contact Details for the Lecturer(s)

Dokuz Eylul University, Faculty of Science, Department of Chemistry e-mail: derya.topkaya@deu.edu.tr

Office Hours

Tuesday, Thursday 15.00-17.00

Work Placement(s)

None

Workload Calculation

Activities Number Time (hours) Total Work Load (hours)
Lectures 11 3 33
Preparations before/after weekly lectures 10 3 30
Preparation for final exam 1 60 60
Preparing assignments 1 75 75
Final 1 3 3
TOTAL WORKLOAD (hours) 201

Contribution of Learning Outcomes to Programme Outcomes

PO/LOPO.1PO.2PO.3PO.4PO.5PO.6PO.7PO.8PO.9PO.10PO.11
LO.13333333333
LO.22222222
LO.32222222
LO.42222222
LO.52322222