COURSE UNIT TITLE

: IONIC LIQUIDS

DEGREE PROGRAMMES

Description of Individual Course Units

Course Unit Code Course Unit Title Type Of Course D U L ECTS
KIM 6061 IONIC LIQUIDS ELECTIVE 3 0 0 8

Offered By

Graduate School of Natural and Applied Sciences

Level of Course Unit

Second Cycle Programmes (Master's Degree)

Course Coordinator

PROFESSOR DOCTOR SERAP ALP

Offered to

Chemistry
Chemistry
Chemistry

Course Objective

As a new class of compounds, Ionic liquids have become an imported topic since 1990s. The number of studies published on this topic has grown almost exponentially. Due to their unique chemical characteristics, ionic liquids were designed as greener solvents to replace conventional volatile solvents that were believed to result in photochemical smog, ozone depletion, and global climate change. Ionic liquids are showing increasingly promising perspectives in the diverse fields of synthesis and industrial application. The aim of this course is to introduce students ionic liquids, their synthesis, properties and applications.

Learning Outcomes of the Course Unit

1   Have knowledge of the alternative solvents used in chemical applications
2   Have knowledge of the Philosophy of the Environment, Pollution Prevention and Green Chemistry,
3   Have knowledge of the Synthesis, Purification and Characterization of Ionic Liquids
4   Have knowledge of the Room Temperature Ionic Liquids (RTILS)
5   Interpret all the reactions of the Ionic Liquids

Mode of Delivery

Face -to- Face

Prerequisites and Co-requisites

None

Recomended Optional Programme Components

None

Course Contents

Week Subject Description
1 Introduction, The Need for Alternative Solvents, Philosophy of the Environment,Pollution Prevention and Green Chemistry, Chemical Practice and Solvent Usage,
2 Introduces the history of ionic liquids as green solvents and discusses the synthesis of ionic liquids and their effects and properties
3 Safety Considerations, Life Cycle Assessment and Green Metrics, Environmental, Health and Safety Properties
4 Synthesis, Purification and Characterization of Ionic Liquids
5 First part of Ionic Liquids in Organic Synthesis: Effects on Rate and Selectivity, Ionic Liquid Effects on Reactions Proceeding through Isopolar and Radical Transition States, Ionic Liquid Effects on Energy Transfer, Hydrogen Transfer and Electron Transfer Reactions, Ionic Liquid Effects on Diels Alder Reactions
6 Room Temperature Ionic Liquids (RTILS) and Eutectic Mixtures, Introduction and Chemical Examples, Extractions using RTILS, Electrochemistry, Synthesis, Biocatalysis, Polymer Synthesis and Processing in Selected Unconventional Uses of RTILs
7 Ionic Liquid Structure-Induced Effects on Organic Reactions
8 Midterm exam
9 Second Part of Ionic Liquids in Organic Synthesis: Effects on Rate and Selectivity, Ionic Liquid Effects on Reactions Proceeding through Isopolar and Radical Transition States, Ionic Liquid Effects on Energy Transfer, Hydrogen Transfer and Electron Transfer Reactions, Ionic Liquid Effects on Diels Alder Reactions
10 Ionic Liquid Effects on Reactions Proceeding through Dipolar Transition States, Nucleophilic Substitution Reactions, Electrophilic Addition Reactions, Electrophilic Substitution Reactions
11 Stoichiometric Organic Reactions and Acid-catalyzed Reactions in Ionic Liquids, Electrophilic Reactions, Nucleophilic Reactions, Electrocyclic Reactions, Addition Reactions (to C=C and C=O Double Bonds), Condensation Reactions
12 Polymer synthesis in Ionic Liquids, Acid- catalized cationic polymerization and oligomerization, free radical polymerization, other polymerizations
13 Industrial applications of ionic liquids, Ionic liquids in chemical proseses.
14 Project presentation

Recomended or Required Reading

-Peter Wasserscheid and Tom Welton Ionic Liquids in Synthesis Second, Completely Revised and Enlarged Edition, Volume 1, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim ISBN 978-3-527-31239-9, 2008
- Francesca M. Kerton Alternative Solvents for Green Chemistry , Published by The Royal Society of Chemistry, Cambridge CB4 0WF, UK ISBN: 978-0-85404-163-3, 2009

Planned Learning Activities and Teaching Methods

Presentation

Assessment Methods

SORTING NUMBER SHORT CODE LONG CODE FORMULA
1 MTE MIDTERM EXAM
2 ASG ASSIGNMENT
3 PRS 1 PRESENTATION 1
4 PRS 2 PRESENTATION 2
5 FIN FINAL EXAM
6 FCG FINAL COURSE GRADE MTE * 0.20 +ASG * 0.20 + PRS 1 * 0.15 + PRS 2 * 0.15 + FIN * 0.30
7 RST RESIT
8 FCGR FINAL COURSE GRADE (RESIT) MTE * 0.20 +ASG * 0.20 + PRS 1 * 0.15 + PRS 2 * 0.15 + RST * 0.30


*** Resit Exam is Not Administered in Institutions Where Resit is not Applicable.

Further Notes About Assessment Methods

None

Assessment Criteria

Student will be assessed with homework presentation, midterm exam and questions which will be asked
in final exam.

Language of Instruction

Turkish

Course Policies and Rules

During the semester, the responsibility to continues 70% of the courses is student s
self-owned. And must be observed the specified time about course times. Unethical
behavior that may occur in class and on exams, will be acting within the framework of
the relevant regulations. Teaching and examination implementation principles
regulations of D.E.Ü Graduate School of Natural and Applied Sciences can be found at
Graduate School of Natural and Applied Sciences web page.

Contact Details for the Lecturer(s)

To be announced.

Office Hours

To be announced.

Work Placement(s)

None

Workload Calculation

Activities Number Time (hours) Total Work Load (hours)
Lectures 14 3 42
Preparation for midterm exam 1 40 40
Preparation before/after weekly lectures 10 2 20
Preparation for Final Exam 1 50 50
Preparing project preparation 1 40 40
Midterm exam 1 3 3
Final exam 1 3 3
TOTAL WORKLOAD (hours) 198

Contribution of Learning Outcomes to Programme Outcomes

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CONTACT INFORMATION
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Phone: +90(232) 412 12 12 - Fax: +90 (232) 464 81 35

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