COURSE UNIT TITLE

: PERICYCLIC REACTIONS

DEGREE PROGRAMMES

Description of Individual Course Units

Course Unit Code Course Unit Title Type Of Course D U L ECTS
KIM 4224 PERICYCLIC REACTIONS ELECTIVE 2 0 0 4

Offered By

Chemistry

Level of Course Unit

First Cycle Programmes (Bachelor's Degree)

Course Coordinator

PROFESSOR DOCTOR SERAP ALP

Offered to

Course Objective

The aim of this course is to provide students to understand thermal and photochemical mechanisms of molecular orbital symmetry reaction formation, to present their diversity from ionic and radical mechanisms with teoretical and practical applications, to bring students to level to associate them with natural reaction processes.

Learning Outcomes of the Course Unit

1   Be able to to understand thermal and photochemical mechanisms of molecular orbital symmetry reaction formation, to present their diversity from ionic and radical mechanisms with teoretical and practical applications, to bring students to level to associate them with natural reaction processes
2   Will be able to understand types of thermal inversion and the elimination reaction, will have information about Cope, Degenerate Cope, Claisen, para Claisen conversion, cyclic elimination,Ene and pyrolysis reaction types
3   Will have information about -cleavage, -hydrogen detachment, photoreduction mechanisms which are formed by photochemical excitement
4   Will have information about photochemistry of different compounds and photochemical reaction mechanisms
5   Will have information about molecular orbital symmetry of unimolecular reactions, stereochemistry and cyclic addition reactions

Mode of Delivery

Face -to- Face

Prerequisites and Co-requisites

None

Recomended Optional Programme Components

None

Course Contents

Week Subject Description
1 Thermal inversion and elimination reactions
2 Cope rearrangement, Degenerate Cope rearrangement
3 Claisen rearrangement, para Claisen rearrangement
4 Cyclic elimination reactions
5 Ene reaction, pyrolysis
6 Homework presentation
7 Homework presentation
8 Mid-term exam
9 Photochemical excitation and reactions
10 -cleavage, -hydrogen cleavage
11 Photoreduction
12 Cyclic addition reactions
13 Homework presentation
14 Homework presentation

Recomended or Required Reading

Ana kaynak: Organik Kimya Reaksiyon Mekanizmaları, Prof.Dr. Metin Balcı, Türkiye Bilimler Akademisi (TÜBA) Yayınevi, Ankara, 2008
Pericyclic Reactions, Ian Fleming, Oxford, 1998
Diğer ders materyalleri: Kaynak kitapların ve internet ortamında yayınlanan ppt sunumları

Planned Learning Activities and Teaching Methods

Presentation, Lecture, question and answer technique, homework, examples

Assessment Methods

SORTING NUMBER SHORT CODE LONG CODE FORMULA
1 MTE MIDTERM EXAM
2 ASG ASSIGNMENT
3 FINS FINAL EXAM
4 FCG FINAL COURSE GRADE MTE * 0.30 + ASG * 0.20 + FIN * 0.50
5 RST RESIT
6 FCGR FINAL COURSE GRADE (RESIT) MTE * 0.30 + ASG * 0.20 + RST * 0.50


*** Resit Exam is Not Administered in Institutions Where Resit is not Applicable.

Further Notes About Assessment Methods

None

Assessment Criteria

Student will be evaluated with midterm exams, homework presentation and final exam.

Language of Instruction

Turkish

Course Policies and Rules

To continue 70% of the classes throughout the semester is students own responsibility. The specified class times must be complied with. Unethical behavior that may occur in class and on exams, will be acting within the framework of the relevant regulations. D.E.U. Science Faculty implementation principles of teaching and examination regulations can be found at http://web.deu.edu.tr/fen

Contact Details for the Lecturer(s)

D.E.U. Science Faculty Department of Chemistry
e-mail: serap.alp@deu.edu.tr, gulsiye.ozturk@deu.edu.tr

Office Hours

Every days 16.00-16.30

Work Placement(s)

None

Workload Calculation

Activities Number Time (hours) Total Work Load (hours)
Lectures 13 2 26
0
Preparation for final exam 1 18 18
Preparation for midterm exam 1 16 16
Preparations before/after weekly lectures 13 2 26
Preparing presentations 1 10 10
0
Final 1 2 2
Midterm 1 2 2
TOTAL WORKLOAD (hours) 100

Contribution of Learning Outcomes to Programme Outcomes

PO/LOPO.1PO.2PO.3PO.4PO.5PO.6PO.7PO.8PO.9PO.10PO.11PO.12PO.13PO.14PO.15PO.16PO.17
LO.14343222
LO.24343222
LO.34343222
LO.44343222
LO.54343222

CONTACT INFORMATION
Dokuz Eylül Üniversitesi Cumhuriyet Bulvarı No: 144 35210 Alsancak / İZMİR
Phone: +90(232) 412 12 12 - Fax: +90 (232) 464 81 35

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