COURSE UNIT TITLE

: THERMODYNAMICS OF SOLUTIONS

Description of Individual Course Units

Course Unit Code Course Unit Title Type Of Course D U L ECTS
MME 2004 THERMODYNAMICS OF SOLUTIONS COMPULSORY 3 0 0 5

Offered By

Metallurgical and Materials Engineering

Level of Course Unit

First Cycle Programmes (Bachelor's Degree)

Course Coordinator

ASSOCIATE PROFESSOR ESRA DOKUMACI ALKAN

Offered to

Metallurgical and Material Engineering Scientific Preparatory (Phd)
Metallurgical and Material Engineering Scientific Preparatory (Msc)
Metallurgical and Materials Engineering

Course Objective

The course aims to give thermodynamic properties and equations of solutions, to investigate the behavior of the solutions and the reactions under different conditions, to get knowledge about relationship between the phase equilibrium diagrams and free energy curves of solutions, to calculate some properties using measurable properties and to utilize the thermodynamic properties of solutions on the design of metallurgical processes.

Learning Outcomes of the Course Unit

1   Explain the thermodynamic properties of solutions and their components
2   Determine the thermodynamic properties of components in a binary system by using the partial molar properties of the solution
3   Calculate the thermodynamic properties of ideal solutions in binary systems
4   Calculate the thermodynamic properties of non-ideal and regular solutions in binary systems
5   Evaluate the relationship between the free energy - composition curves and binary phase stability diagrams
6   Evaluate the thermodynamic data obtained by the experimental determination methods
7   Investigate interactions of the components in a dilute multi-component solution

Mode of Delivery

Face -to- Face

Prerequisites and Co-requisites

MME 2003 - METALLURGICAL THERMODYNAMICS

Recomended Optional Programme Components

None

Course Contents

Week Subject Description
1 Introduction, units and abbreviations in thermodynamics, four basic equations in metallurgical thermodynamic
2 Formation of solutions, determining partial molar properties of solutions, Gibbs-Duhem equation
3 Ideal and non-ideal solutions, activity and activity coefficient, Raoult's and Henry's Laws
4 Application of Gibbs-Duhem equation, dilute solutions
5 Chemical bonds in solutions, regular solutions, excess free energy concept
6 Problem section
7 Gibbs free energy - composition relationship in binary system
8 Activity - composition relationship in binary system
9 The relationship between the Gibbs Free Energy-Composition Curves of phases and phase equilibrium diagrams, some examples demonstrating the relationship
10 Experimental determination of curves of activity and of free energy
11 Problem section
12 Alternative standard states
13 Dilute solutions containing multi-components
14 Gas solubility in metal alloys

Recomended or Required Reading

1) Gaskell, D. R., & Laughlin, D. E. (2017). Introduction to the Thermodynamics of Materials. CRC press.
2) Aydın,S. (2014). Metalurji ve Malzeme Mühendisleri için Termodinamik.Literatür Kitabevi, Istanbul.
3) Aytekin, V.(1980). Metalurji Termodinamiği, I.T.Ü. Metalurji Fakültesi Ofset Baskı Atölyesi, Istanbul.
4) DeHoff, R. T. (1993). Thermodynamics in Materials Science McGraw Hill. Inc., New York, NY.
5) Ragone, D. V. (1995). Thermodynamics of Materials, JohnWiley & Sons. Inc., NY, USA.
6) Upadhyaya, G. S., & Dube, R. K. (2013). Problems in Metallurgical Thermodynamics and Kinetics: International Series on Materials Science and Technology (Vol. 25). Elsevier.

Planned Learning Activities and Teaching Methods

Lecturing, exams and homeworks

Assessment Methods

SORTING NUMBER SHORT CODE LONG CODE FORMULA
1 MTE MIDTERM EXAM
2 ASG ASSIGNMENT
3 QUZ QUIZ
4 FIN FINAL EXAM
5 FCGR FINAL COURSE GRADE (RESIT) MTE * 0.25 + ASG" * 0.25 + QUZ * 0.10 + FIN * 0.40
6 RST RESIT
7 FCGR FINAL COURSE GRADE (RESIT) MTE * 0.25 + ASG" * 0.25 + QUZ * 0.10 + RST * 0.40


*** Resit Exam is Not Administered in Institutions Where Resit is not Applicable.

Further Notes About Assessment Methods

Midterm exams and final exams related to learning outcomes are given as usual closed book and closed note written exams. Homework results will also be included in the term time assessment.

Assessment Criteria

LO1-7 will be evaluated by the questions in the exams.
LO3-5 are also evaluated by homework.

Language of Instruction

English

Course Policies and Rules

Lectures and examinations are carried out with respect to regulation of Engineering Faculty of Dokuz Eylul University, named "Principles of Education and Examination Practice".

If the homeworks are cited without reference directly from another source or quoted directly from other students, the relevant study is excluded from the evaluation.

Contact Details for the Lecturer(s)

Assis. Prof. Dr. Esra DOKUMACI
Phone: 02323017468
E-mail: esra.dokumaci@deu.edu.tr

Assis. Prof. Dr. Murat ALKAN
Phone: 02323017464
E-mail: alkan.murat@deu.edu.tr

Office Hours

The student counseling hours are stated in the weekly course schedule at the door of the academic staff.

Work Placement(s)

None

Workload Calculation

Activities Number Time (hours) Total Work Load (hours)
Lectures 14 3 42
Preparations before/after weekly lectures 14 2 28
Preparation for midterm exam 1 10 10
Preparation for final exam 1 14 14
Preparing assignments 1 16 16
Preparation for quiz etc. 2 5 10
Final 1 2 2
Midterm 1 2 2
Quiz etc. 2 1 2
TOTAL WORKLOAD (hours) 126

Contribution of Learning Outcomes to Programme Outcomes

PO/LOPO.1PO.2PO.3PO.4PO.5PO.6PO.7PO.8PO.9PO.10PO.11PO.12
LO.153
LO.244
LO.3444
LO.4444
LO.543244
LO.633
LO.734